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・ Tellurite (ion)
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Tellurium tetrafluoride
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Tellurium tetrafluoride : ウィキペディア英語版
Tellurium tetrafluoride

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Tellurium tetrafluoride, TeF4, is a stable, white, hygroscopic crystalline solid and is one of two fluorides of tellurium. The other binary fluoride is tellurium hexafluoride.〔''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5〕 The widely reported Te2F10 has been shown to be F5TeOTeF5 〔 There are other tellurium compounds that contain fluorine, but only the two mentioned contain solely tellurium and fluorine. Tellurium difluoride, TeF2, and ditellurium fluoride, Te2F are not known.〔
==Preparation==
Tellurium tetrafluoride can be prepared by the following reaction:
:TeO2 + 2SF4 → TeF4 + 2SOF2
It is also prepared by reacting nitryl fluoride with tellurium or from the elements at 0 °C or by reacting selenium tetrafluoride with tellurium dioxide at 80 °C.
Fluorine in nitrogen can react with TeCl2 or TeBr2 to form TeF4. PbF2 will also fluorinate tellurium to TeF4.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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